I have been shooting "Lead Free" copper bullets for about 12 years when I purchased some and reloaded one of my rifles for them to see how they worked at the range. The issue I had with these "Early" Solid Copper slug is I could not get the velocities from them like you could do with lead. Also, after shooting just a few, when I cleaned the rifle all my patches came out green. This was because of copper fowling, where I never got that using copper jacketed lead bullets.
Many years ago I found this, printed it out and put it on the wall above my reloading table. In it there are several "Lead Free" bullets., and you can see how all the bullets perform at different velocities.